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Author: Admin | 2025-04-27
MSI under reaction conditions, which has led to the designation of (sub)classifications of MSI deserving to be critically and systematically evaluated. These include dynamic restructuring under alternating redox and reaction conditions, adsorbate-induced MSI, and evidence of strong interactions in oxide-supported metal oxide catalysts. Here, we review recent literature on MSI in oxide-supported metal particles to provide an up-to-date understanding of the underlying physicochemical principles that dominate the observed effects in supported metal atomic, cluster, and nanoparticle catalysts. Critical evaluation of different subclassifications of MSI is provided, along with discussions on the formation mechanisms, theoretical and characterization advances, and tuning strategies to manipulate catalytic reaction performance. We also provide a perspective on the future of the field, and we discuss the analysis of different MSI effects on catalysis quantitatively. Supplementary files Supplementary information PDF (1025K) Article information DOI https://doi.org/10.1039/D4CS00527A Article type Review Article Submitted 02 Aug 2024 First published 02 Oct 2024 This article is Open Access Download Citation Chem. Soc. Rev., 2024,53, 10450-10490 Permissions Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis D. Leybo, U. J. Etim, M. Monai, S. R. Bare, Z. Zhong and C. Vogt, Chem. Soc. Rev., 2024, 53, 10450 DOI: 10.1039/D4CS00527A This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given. Read more about how to correctly acknowledge RSC content. Social activity Spotlight Advertisements
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